Ускоренный массоперенос при интенсивной пластической деформации и ионной имплантации
DOI:
https://doi.org/10.54708/26587572_2026_832664Ключевые слова:
Массоперенос, интенсивная пластическая деформация, интенсивная ионная имплантация, металлические сплавы, кислородАннотация
При интенсивной пластической деформации (ИПД) часто наблюдаются фазовые превращения, которые сопровождаются ускоренным массопереносом. В сплавах алюминия, меди и титана при ИПД наблюдалось равновесие между образованием и распадом пересыщенного твердого раствора. При этом происходит ускоренный массоперенос атомов матрицы и растворенного компонента. Были проведены оценки эффективного коэффициента диффузии для такого массопереноса, вызванного ИПД. Обнаружено, что эффективный коэффициент диффузии Deq при ИПД на 8-12 порядков величины превышает значения коэффициента объёмной термической диффузии Dv при температуре ИПД эксперимента (обычно это 300 К). Это связано, по всей видимости, с высоким содержанием дефектов решётки в стационарном состоянии, возникающим при ИПД. Таким образом, величина Deq, наблюдаемая в ходе ИПД при TSPD = 300 К сравнима с величиной Dv при некоторой эффективной температуре Teff, намного превышающей температуру ИПД эксперимента TSPD. Недавно нами была разработана установка для низкоэнергетической сильноточной ионной имплантации в ускорителе с Холловским током. Она, в частности, позволяет проводить имплантацию ионов кислорода и азота с плотностью ионного тока на несколько порядков выше, чем в стандартных методах ионной имплантации. В результате, например, глубина проникновения ионов кислорода в титан при энергии 1 кВ в нашем случае вместо стандартных 20 нанометров составляет около 20 микрометров. По нашему мнению, существует определённое сходство между деформационно-стимулированным и ионно-стимулированным массопереносом в сильно неравновесных условиях.Библиографические ссылки
Valiev R.Z., Islamgaliev R.K., Alexandrov I.V. Bulk nanostructured materials from severe plastic deformation // Progress in Materials Science. 45, 103–189 (2000). DOI: 10.1016/S0079-6425(99)00007-9.
Teitel‘ E.I., Metlov L.S., Gunderov D.V., Korznikov A.V. On the structural and phase transformations in solids induced by severe plastic deformation // Physics of Metals and Metallography. 113, 1162–1168 (2012). DOI: 10.1134/S0031918X12120095.
Sauvage X., Chbihi A., Quelennec X. Severe plastic deformation and phase transformations // Journal of Physics. 240, 012003 (2010). DOI: 10.1088/1742-6596/240/1/012003
Zhang H.W., Ohsaki S., Mitao S., et al. Microstructural investigation of white etching layer on pearlite steel rail // Materials Science and Engineering A. 421, 191–199 (2006). DOI: 10.1016/j.msea.2006.01.033.
Lojkowski W., Djahanbakhsh M., Burkle G., et al. Nanostructure formation on the surface of railway tracks // Materials Science and Engineering A. 303, 197–208 (2001). DOI: 10.1016/S0921-5093(00)01947-X.
Hono K., Ohnuma M., Murayama M., et al. Cementite decomposition in heavily drawn pearlite steel wire // Scripta Materialia. 44, 977–983 (2001). DOI: 10.1016/S1359-6462(00)00690-4.
Taniyama A., Takayama T., Arai M., Hamada T. Structure analysis of ferrite in deformed pearlitic steel by means of X-ray diffraction method with synchrotron radiation // Scripta Materialia. 51, 53–58 (2004). DOI: 10.1016/j.scriptamat.2004.03.018.
Gavriljuk V.G. Decomposition of cementite in pearlitic steel due to plastic deformation // Materials Science and Engineering A 345, 81–89 (2003). DOI: 10.1016/S0921-5093(02)00358-1.
Sauvage X., Quelennec X., Malandain J.J., Pareige P. Nanostructure of a cold drawn tempered martensitic steel // Scripta Materialia. 54, 1099–1103 (2006). DOI: 10.1016/j.scriptamat.2005.11.068.
Teplov V.A., Pilugin V.P., Gaviko V.S., Chernyshov E.G. Non-equilibrium solid-solution and nanocrystal structure of Fe-Cu alloy after plastic deformation under pressure // Philosophical Magazine B. 68, 877–881 (1993). DOI: 10.1080/13642819308217944.
Stolyarov V.V., Lapovok R., Brodova I.G., Thomson P.F. Ultrafine-grained Al–5 wt.% Fe alloy processed by ECAP with backpressure // Materials Science and Engineering A. 357, 159–167 (2003). DOI: 10.1016/S0921-5093(03)00215-6.
Sauvage X., Wetscher F., Pareige P. Mechanical alloying of Cu and Fe induced by severe plastic deformation of a Cu–Fe composite // Acta Materialia. 53 (2005) 2127–2135. DOI: 10.1016/j.actamat.2005.01.024.
Straumal B.B., Baretzky B., Mazilkin A.A., et al. Formation of nanograined structure and decomposition of supersaturated solid solution during high pressure torsion of Al–Zn and Al–Mg alloys // Acta Materialia. 52, 4469–4478 (2004). DOI: 10.1016/j.actamat.2004.06.006.
Mazilkin A.A., Straumal B.B., Rabkin E., et al. Softening of nanostructured Al–Zn and Al–Mg alloys after severe plastic deformation // Acta Materialia. 54, 3933–3939 (2006). DOI: 10.1016/j.actamat.2006.04.025.
Straumal B.B., Protasova S.G., Mazilkin A.A., et al. Severe plastic deformation on powder metallurgy Cu–Al–Ni shape memory alloys // Journal of Materials Science. 47, 360–367 (2012). DOI: 10.1016/j.matpr.2015.07.390.
Cepeda-Jiménez C.M., García-Infanta J.M., Zhilyaev A.P., et al. Influence of the thermal treatment on the deformation-induced precipitation of a hypoeutectic Al–7 wt% Si casting alloy deformed by high-pressure torsion // Journal of Alloys and Compounds. 509, 636–643 (2011). DOI: 10.1016/j.jallcom.2010.09.122
Ivanisenko Y., MacLaren I., Sauvage X., et al. Shear-induced α → γ transformation in nanoscale Fe–C composite // Acta Materialia. 54, 1659–1669 (2006). DOI: 10.1016/j.actamat.2005.11.034.
Sauvage X., Ivanisenko Y. The role of carbon segregation on nanocrystallisation of pearlitic steels processed by severe plastic deformation // Journal of Materials Science. 42, 1615–1621 (2007). DOI: 10.1007/s10853-006-0750-z.
Ivanisenko Y., Lojkowski W., Valiev R.Z., Fecht H.J. The mechanism of formation of nanostructure and dissolution of cementite in a pearlitic steel during high pressure torsion // Acta Materialia. 51, 5555–5570 (2003). DOI: 10.1016/S1359-6454(03)00419-1.
Sagaradze V.V., Morozov S.V., Shabashov V.A., et al. Anomalous diffusion phase transformations in steels upon severe cold deformation // Physics of Metals and Metallography. 66, 328–338 (1988). DOI: 10.1134/S0031918X11020256.
Straumal B.B., Mazilkin A.A., Protasova S.G., et al. Fe–C nanograined alloys obtained by high-pressure torsion: Structure and magnetic propertie // Materials Science and Engineering A. 503, 185–189 (2009). DOI: 10.1016/j.msea.2008.03.052.
Sagaradze V.V., Shabashov V.A. Deformationinduced anomalous phase transformations in nanocrystalline FCC Fe-Ni based alloys // Nanostructured Materials. 9, 681–684 (1997). DOI: 10.1016/S0965-9773(97)00150-1.
Murayama M., Hono K., Horita Z. Microstructure evolution in an Al-1.7at%Cu alloy deformed by equal channel angular pressing // Materials Transactions, JIM. 40, 938–941 (1999). DOI: 10.2320/matertrans1989.40.938.
Ohsaki S., Kato S., Tsuji N., et al. Bulk mechanical alloying of Cu–Ag and Cu/Zr two-phase microstructures by accumulative roll-bonding process // Acta Materialia. 55, 2885–2895 (2007). DOI: 10.1016/j.actamat.2006.12.027.
Sauvage X., Pippan R. Nanoscaled structure of a Cu–Fe composite processed by high-pressure torsion // Materials Science and Engineering A. 410–411, 345–347 (2005). DOI: 10.1016/j.msea.2005.08.122.
Sauvage X., Genevois C., Da Costa G., Pantsyrny V. Atomic scale characterization of deformation-induced interfacial mixing in a Cu/V nanocomposite wire // Scripta Materialia. 61, 660–663 (2009). DOI: 10.1016/j.scriptamat.2009.06.007.
Sauvage X., Lefebvre W., Genevois C., et al. Complementary use of transmission electron microscopy and atom probe tomography for the investigation of steels nanostructured by severe plastic deformation // Scripta Materialia. 60, 1056–1061 (2009). DOI: 10.1016/j.scriptamat.2009.02.019.
Straumal B.B., Dobatkin S.V., Rodin A.O., et al. Structure and properties of nanograined Fe–C alloys after severe plastic deformation // Advanced Engineering Materials. 13, 463–469 (2011). DOI: 10.2320/matertrans. MD201111.
Korznikov A.V., Dimitrov O., Korznikova G.F., et al. Nanocrystalline structure and phase transformation of the intermetallic compound TiAl processed by severe plastic deformation // Nanostructured Materials. 11, 17–23 (1999). DOI: 10.1016/S0965-9773(98)00157-3.
Korznikov A.V., Tram G., Dimitrov O., et al. The mechanism of nanocrystalline structure formation in Ni3Al during severe plastic deformation // Acta Materialia. 49, 663–671 (2001). DOI: 10.1016/S1359-6454(00)00345-1.
Rentenberger C., Karnthaler H.P. Extensive disordering in long-range-ordered Cu3Au induced by severe plastic deformation studied by transmission electron microscopy // Acta Materialia. 56, 2526–2530 (2008). DOI: 10.1016/j.actamat.2008.01.035.
Sergueeva A.V., Song C., Valiev R.Z., Mukherjee A.K. Structure and properties of amorphous and nanocrystalline NiTi prepared by severe plastic deformation and annealing // Materials Science and Engineering A. 339, 159–165 (2003). DOI: 10.1016/S0921-5093(02)00122-3.
Prokoshkin S.D., Khmelevskaya I.Yu., Dobatkin S.V., et al. Alloy composition, deformation temperature, pressure and post-deformation annealing effects in severely deformed Ti–Ni based shape memory alloys // Acta Materialia. 53, 2703–2714 (2005). DOI: 10.1016/j.actamat.2005.02.032.
Sauvage X., Renaud L., Deconihout B., et al. Solid state amorphization in cold drawn Cu/Nb wires // Acta Materialia. 49, 389–394 (2001). DOI: 10.1016/S1359-6454(00)00338-4.
Miyazaki T., Terada D., Miyajima Y., et al. Synthesis of non-equilibrium phases in immiscible metals mechanically mixed by high pressure torsion // Journal of Materials Science. 46, 4296–4301 (2011). DOI: 10.1007/s10853-010-5240-7.
Mazilkin A.A., Abrosimova G.E., Protasova S.G., et al. Transmission electron microscopy investigation of boundaries between amorphous “grains” in Ni50Nb20Y30 alloy // Journal of Materials Science. 46, 4336–4342 (2011). DOI: 10.1007/s10853-011-5304-3.
Stolyarov V.V., Gunderov D.V., Popov A.G., et al. Structure evolution and changes in magnetic properties of severe plastic deformed Nd(Pr)–Fe–B alloys during annealing // Journal of Alloys and Compounds. 281, 69–71 (1998). DOI: 10.1016/S0925-8388(98)00774-9.
Matsuura Y., Hirosawa S., Yamamoto H., et al. Phase diagram of the Nd-Fe-B ternary system // Japanese Journal of Applied Physics. Part 2 – Letters. 24, L635–L637 (1985). DOI: 10.1143/JJAP.24.L635.
Straumal B.B., Mazilkin A.A., Protasova S.G., et al. Formation of two amorphous phases in the Ni60Nb18Y22 alloy after high pressure torsion // Kovove Materialy – Metallic Materials. 49, 17–22 (2011). DOI: 10.4149/km-2011-1-17.
Révész Á., Hóbor S., Lábár J.L., et al. Partial amorphization of a Cu–Zr–Ti alloy by high pressure torsion // Journal of Applied Physics.100, 103522 (2006). DOI: 10.1063/1.2388868.
MacLaren I., Ivanisenko Y., Valiev R.Z., Fecht H.J. Reverse martensitic transformation of ferrite to austenite under severe plastic deformation // Journal of Physics. 26, 335–338 (2006). DOI: 10.1088/1742-6596/26/1/081.
Ivanisenko Y., MacLaren I., Sauvage X., et al. Phase transformations in pearlitic steels induced by severe plastic deformation // Solid State Phenomena. 114, 133–144 (2006). DOI: 10.4028/www.scientific.net/SSP.114.133.
Ivanisenko Y., MacLaren I., Sauvage X., et al. Shear-induced α → γ transformation in nanoscale Fe–C composite // Acta Materialia. 54, 1659–1669 (2006). DOI: 10.1016/j.actamat.2005.11.034.
Zhilyaev A.P., Sabirov I., González-Doncel G., et al. Effect of Nb additions on the microstructure, thermal stability and mechanical behavior of high pressure Zr phases under ambient conditions // Materials Science and Engineering A. 528, 3496–3505 (2011). DOI: 10.1016/j.msea.2011.01.062
Zhilyaev A.P., Sharafutdinov A.V., Pérez-Prado M.T. Phase transformations during high-pressure torsion of pure Zr and of a Zr-2.5%Nb alloy // Advanced Engineering Materials. 12, 754–757 (2010). DOI: 10.1002/adem.200900348.
Zhilyaev A.P., Gálvezc F., Sharafutdinov A.V., Pérez-Prado M.T. Influence of the high pressure torsion die geometry on the allotropic phase transformations in pure Zr // Materials Science and Engineering A. 527, 3918–3928 (2010). DOI: 10.1016/j.msea.2010.02.066.
Pérez-Prado M.T., Sharafutdinov A.V., Zhilyaev A.P. Thermal stability of pure bcc Zr fabricated by high pressure torsion // Materials Letters. 64, 211–214 (2010). DOI: 10.1016/j.matlet.2009.10.049.
Pérez-Prado M.T., Zhilyaev A.P. First experimental observation of shear induced hcp to bcc transformation in pure Zr // Physical Review Letters. 102, 175504 (2009). DOI: 10.1103/PhysRevLett.102.175504.
Edalati K., Horita Z., Mine Y. High-pressure torsion of hafnium // Materials Science and Engineering A. 527, 2136–2141 (2010). DOI: 10.1016/j.msea.2009.11.060.
Edalati K., Horita Z., Yagi S., Matsubara E. Allotropic phase transformation of pure zirconium by highpressure torsion // Materials Science and Engineering A. 523, 277–281 (2009). DOI: 10.1016/j.msea.2009.07.029.
Edalati K., Matsubara E., Horita Z. Processing pure Ti by high-pressure torsion in wide ranges of pressures and strain // Metallurgical and Materials Transactions A. 40, 2079–2086 (2009). DOI: 10.1007/s11661-009-9890-5.
Ivanisenko Y., Kilmametov A., Roesner H., Valiev R.Z. Evidence of α→ ω phase transition in titanium after high pressure torsion // International Journal of Materials Research. 99,36–41 (2008). DOI: 10.3139/146.101606.
Glezer A.M., Plotnikova M.R., Shalimova A.V., Dobatkin S.V. Severe plastic deformation of amorphous alloys: I. Structure and mechanical properties // Bulletin of the Russian Academy of Sciences: Physics. 73, 1233–1236 (2009). DOI: 10.3103/S1062873809090123.
Hóbor S., Révész Á., Zhilyaev A.P., Kovácz Zs. Different nanocrystallization sequence during high pressure torsion and thermal treatments of amorphous Cu60Zr20Ti20 alloy // Reviews on Advanced Materials Science. 18, 590–592 (2008).
Kovács Zs., Henits P., Zhilyaev A.P., Révész Á. Deformation induced primary crystallization in a thermally non-primary crystallizing amorphous Al85Ce8Ni5Co2 alloy // Scripta Materialia. 54, 1733–1737 (2006). DOI: 10.1016/j.scriptamat.2006.02.004.
Abrosimova G.E., Aronin A.S., Dobatkin S.V., et al. The formation of nanocrystalline structure in amorphous Fe-Si-B alloy by severe plastic deformation // Journal of Metastable and Nanocrystalline Materials. 24, 69–72 (2005). DOI: 10.4028/www.scientific.net/JMNM.24-25.69.
Révész Á., Schafler E., Kovács Zs. Structural anisotropy in a bulk metallic glass Zr57Ti5Cu20Al10Ni8 deformed by high pressure torsion at room temperature // Applied Physics Letters. 92, 011910 (2008). DOI: 10.1063/1.2830992.
Hóbor S., Kovács Zs., Zhilyaev A.P., et al. High pressure torsion of Cu-based metallic glasses // Journal of Physics. 240, 012153 (2010). DOI: 10.1088/1742-6596/240/1/012153.
Hóbor S., Révész Á., Szabó P.J., et al. High pressure torsion of Cu60Zr30Ti10 amorphous alloy // Journal of Applied Physics. 104, 033525 (2008). DOI: 10.1063/1.2964115.
Henits P., Révész Á., Zhilyaev A.P., Kovács Zs. Severe plastic deformation induced nanocrystallization of melt-spun Al85Y8Ni5Co2 amorphous alloy // Journal of Alloys and Compounds. 461, 195–199 (2008). DOI: 10.1016/j.jallcom.2007.07.049.
Kovács Zs., Henits P., Zhilyaev A.P., et al. Microstructural characterization of the crystallization sequence of a severe plastically deformed Al-Ce-Ni-Co amorphous alloy // Materials Science Forum. 519–521, 1329–1334 (2006). DOI: 10.4028/www.scientific.net/MSF.519-521.1329.
Martin G. Phase stability under irradiation: Ballistic effects // Physical Review B. 30, 1424–1436 (1984). DOI: 10.1103/PhysRevB.30.1424.
Straumal B.B., Mazilkin A.A., Baretzky B., et al. Accelerated diffusion and phase transformations in Co–Cu alloys driven by the severe plastic deformation // Materials Transactions. 53, 63–71 (2012). DOI: 10.2320/matertrans.MD201111.
Straumal B.B., Klinger L.M., Shvindlerman L.S. The influence of pressure on indium diffusion along single tin-germanium interphase boundaries // Scripta Metallurgica. 17, 275–279 (1983). DOI: 10.1016/0036-9748(83)90156-4.
Molodov D.A., Straumal B.B., Shvindlerman L.S. The effect of pressure on migration of <001> tilt grain boundaries in tin bicrystals // Scripta Metallurgica. 18, 207–211 (1984). DOI: 10.1016/0036-9748(84)90509-X.
Thomas G., Mori H., Fujita H. Electron irradiation induced crystalline amorphous transitions in Ni-Ti alloys // Scripta Metallurgica. 16, 589–592 (1982). DOI: 10.1016/0036-9748(82)90276-9.
Beke D.L., Godeny I., Kedves F.J. Diffusion of 65Zn in dilute AlCu, AlCuZn, AlSi, and AlSiZn alloys // Philosophical Magazine A. 47, 281 (1983). DOI: 10.1080/01418618308245224.
Peterson N.L., Rothman S.J. Impurity diffusion in aluminum // Physical Review B. 1, 3264–3272 (1970). DOI: 10.1103/PhysRevB.1.3264.
Rothman S.J., Peterson N.L., Nowicki L.J., Robinson L.C. Tracer diffusion of magnesium in aluminum single crystals // Physica Status Solidi B. 63, K29–K33 (1974). DOI: 10.1002/pssb.2220630151.
Mehrer H. (ed.). Diffusion in Solid Metals and Alloys. Landolt-Börnstein New Series. Gr III. Vol. 26. Berlin: Springer-Verlag,1990.
Schaefer H.-E. Investigation of thermal equilibrium vacancies in metals by positron annihilation // Physica Status Solidi A. 102, 47–65 (1987). DOI: 10.1002/pssa.2211020104.
Divinski S.V., Reglitz G., Rösner H., et al. Ultrafast diffusion channels in pure Ni severely deformed by equal-channel angular pressing // Acta Materialia. 59, 1974–1985 (2011). DOI: 10.1016/j.actamat.2010.11.063.
Amouyal Y., Divinski S.V., Estrin Y., Rabkin E. Short-circuit diffusion in an ultrafine-grained copper–zirconium alloy produced by equal channel angular pressing // Acta Materialia. 55, 5968–5979 (2007). DOI: 10.1016/j.actamat.2007.07.026.
Bellon P., Averback R.S. Nonequilibrium roughening of interfaces in crystals under shear: application to ball milling // Physical Review Letters. 74, 1819–1822 (1995). DOI: 10.1103/PhysRevLett.74.1819.
Straumal B.B., Kilmametov A.R., Kucheev Yu.O., et al. Phase transitions during high pressure torsion of Cu-Co alloys // Materials Letters. 118, 111–114 (2014). DOI: 10.1016/j.matlet.2013.12.042.
Mackliet C.A. Diffusion of iron, cobalt, and nickel in single crystals of pure copper // Physical Review. 109, 1964–1970 (1958). DOI: 10.1103/PhysRev.109.1964.
Fujikawa S., Hirano K.I. Proceedings of Yamada Conference V on Point Defects and Defect Interactions in Metals / Eds. J.I. Takamura, M. Doyama, M. Kiritani. Tokyo: University of Tokyo Press, 1982. P. 554–558.
Surholt T., Herzig Chr. Grain boundary selfdiffusion in Cu polycrystals of different purity // Acta Materialia. 45, 3817–3823 (1997). DOI: 10.1016/S1359-6454(97)00037-2.
Divinski S., Ribbe J., Schmitz G., Herzig Chr. Grain boundary diffusion and segregation of Ni in Cu // Acta Materialia. 55, 3337–3346 (2007). DOI: 10.1016/j.actamat.2007.01.032.
Amouyal Y., Divinski S.V., Estrin Y., Rabkin E. Short-circuit diffusion in an ultrafine-grained copper–zirconium alloy produced by equal channel angular pressing // Acta Materialia. 55, 5968–5979 (2007). DOI: 10.1016/j.actamat.2007.07.026.
Straumal B.B., Kilmametov A.R., Mazilkin A.A., et al. Transformations of Cu(In) supersaturated solid solutions under high-pressure torsion // Materials Letters. 138, 255–258 (2014). DOI: 10.1016/j.matlet.2014.10.009.
Gorbachev V.A., Klotsman S.M., Rabovskiy Ya.A., et al. Indium tracer diffusion in copper // Physics of Metals and Metallography. 34(4), 202–206 (1972). DOI: 10.1070/PU1990v033n01ABEH002405.
Gust W., Predel B., Roll U. Untersuchungen zur diskontinuierlichen ausscheidung in synthetischen Cu-In-Zweikristallen mit 4,6 At.-% In // Acta Metallurgica. 28, 1395–1405 (1980). DOI: 10.1016/0001-6160(80)90008-5.
Straumal B.B., Kilmametov A.R., Kucheev Yu.O., et al. Transformation of Hume-Rothery phases under the action of high pressure torsion // JETP Letters. 100, 376–379 (2014) DOI: 10.1134/S0021364014180106.
Straumal B.B., Pontikis V., Kilmametov A.R., et al. Competition between precipitation and dissolution in Cu–Ag alloys under high pressure torsion // Acta Materialia. 122, 60 (2017). DOI: 10.1016/j.actamat.2016.09.024.
Straumal B.B., Kilmametov A.R., Korneva A., et al. Phase transitions in Cu-based alloys under high pressure torsion // Journal of Alloys and Compounds. 707, 20 (2017). DOI: 10.1016/j.jallcom.2016.12.057.
Straumal B.B., Kilmametov A.R., López G.A., et al. High-pressure torsion driven phase transformations in Cu–Al–Ni shape memory alloys // Acta Materialia. 125, 274–275 (2017). DOI: 10.1016/j.actamat.2016.12.003.
Kilmametov A., Ivanisenko Yu., Mazilkin A.A., et al. The α→ω and β→ω phase transformations in Ti–Fe alloys under high-pressure torsion // Acta Materialia. 144, 337–351 (2018) DOI: 10.1016/j.actamat.2017.10.051.
Straumal B.B., Kilmametov A.R., Ivanisenko Yu., et al. Diffusive and displacive phase transitions in Ti–Fe and Ti–Co alloys under high pressure torsion. // Journal of Alloys and Compounds. 735, 2281–2286 (2018). DOI: 10.1016/j.jallcom.2017.11.317.
Straumal B., Gornakova A., Davdjan G., et al. Review – phase transitions in Ti alloys driven by the high pressure torsion // Materials Transactions. 64, 1820–1832 (2023). DOI: 10.2320/matertrans.MT-MF2022044.
Nakajima H., Koiwa M., Ono S. Diffusion of iron in single crystal α-titanium // Scripta Metallurgica. 17, 1431–1434 (1983). DOI: 10.1016/0036-9748(83)90370-8.
Nakajima H, Ishioka S, Koiwa M. Isotope effect for diffusion of cobalt in single-crystal α-titanium // Philosophical Magazine A. 52, 743–751 (1985). DOI: 10.1080/01418618508242139.
Nakajima H., Koiwa M. Titanium Science and Technology. In: Proceedings 5th International Conference on Titanium. Oberursel: DGM, 1985. P. 1759.