Using the methods of circulation distillation and Rayleigh distillation, the liquid-vapor separation coefficients in the systems tetrakis(trifluorophosphine) nickel – dichloromethane and tetrakis(trifluorophosphine) nickel – pentane at 298 K were determined. For the tetrakis(trifluorophosphine) nickel – dichloromethane system the values αcir and αeff are 4.9 ± 0.8 and 11.7, accordingly, for the tetrakis(trifluorophosphine) nickel – pentane system the values are 4.2 ± 0.4 and 20.3, accordingly. The results obtained are consistent with the results of a theoretical assessment of the values αcir and αeff of the vapor-liquid separation coefficient according to Raoult’s law.
Author Biographies
Troshin Oleg Yurievich, Institute of Chemistry of High-Purity Substances n. a. G. G. Devyatykh, RAS
Senior researcher of the Laboratory of Substances of Special Purity, PhD in Chemistry.Email: troshin@ihps-nnov.ru ORCID: https://orcid.org/0000-0001-6996-1561 Scopus ID: 6604067705
Sozin Andrey Yurievich, Institute of Chemistry of High-Purity Substances n. a. G. G. Devyatykh, RAS
Head of the Laboratory of Analytical Chemistry of High-Purity Substances, Dr. of Chemical Sciences.Email: sozin@ihps-nnov.ru ORCID: https://orcid.org/0000-0002-0237-6998
